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Solvent-effects in chiral transition metal complex: A comparison between the experimental and calculated VCD spectra proves the existence of both Δ and Λ isomers in an acetonitrile solution. However, a significant shift of the equilibrium toward the Λ diastereomer is found for the complex in dimethyl sulfoxide.
erstellt am: 07.03.2014 | von: christian | Kategorie(n): Allgemein, Publications
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